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Iodine-Assisted Assembly of Helical Coordination Polymers of Cucurbituril and Asymmetric Copper(II) Complexes

โœ Scribed by Feng Zhang; Tatsuo Yajima; Yi-Zhi Li; Guo-Zheng Xu; Hui-Lan Chen; Qi-Tao Liu; Osamu Yamauchi

Book ID
102721772
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
749 KB
Volume
117
Category
Article
ISSN
0044-8249

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Iodine has long been paid considerable attention for its fascinating chemical behavior [1, 2] and biological essentiality. [3] The use of iodine as electrical conductor in the synthesis of donor-acceptor charge-transfer materials is well known. [4] In recent years, iodine in various forms has found

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Two novel ladder-like copper(II) compounds, [Cu 2 (histamine) 2 (C 2 O 4 )(ClO 4 ) 2 ] (1) and [Cu 2 (histamine) 2 (C 2 O 4 )(H 2 O) 2 (NO 3 ) 2 ] (2), are prepared. Compound 1 crystallizes in the triclinic space group P1 , with a โ€ซุโ€ฌ 7.450(4) A s , b โ€ซุโ€ฌ 7.519(7) A > , c โ€ซุโ€ฌ 9.646(5) A > , โ€ซุโ€ฌ 85.7