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Iodinated Biaryls Synthesized by the Direct Dehydrodimerization of Iodoarenes Using Phenyliodine(III) Bis(trifluoroacetate) (PIFA)

✍ Scribed by Daniela Mirk; Alexander Willner; Roland Fröhlich; Siegfried R. Waldvogel


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
130 KB
Volume
346
Category
Article
ISSN
1615-4150

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✦ Synopsis


Abstract

Multiply iodinated biaryls can be prepared in yields up to 75% by direct oxidative coupling reaction of the iodinated arenes. The PIFA‐mediated dehydrodimerization is superior to all other known methods. The developed protocol is reliable and easy to perform.