✦ LIBER ✦

Iodide ion promotion of benzyl chloride-borate ester carbonylation reactions

✍ Scribed by Howard Alper; Nathalie Hamel; James B. Woell; David J.H. Smith

Book ID: 104226942
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 127 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95072-x

No coin nor oath required. For personal study only.

✦ Synopsis

Esters are isolated in fine yields from the rhodium(I) catalyzed reaction of bentyl chlorides with borate esters and carbon monoxide, in the presence of potassium iodide. Recently, we have described the use of borate esters to convert benzylic bromides to all

📜 SIMILAR VOLUMES

Synthesis of esters by rhodium(i) cataly

Synthesis of esters by rhodium(i) catalyzed borate ester-benzylic bromide carbonylation reactions

✍ James B. Woell; Howard Alper 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 181 KB

Elimination Reactions of α-Halogenated K

Elimination Reactions of α-Halogenated Ketones. VIII. 1a Efficiency of Chloride Ion and Perchlorate Ion in the Promotion of Dehydrobromination of 2-Benzyl-2-bromo-4,4-dimethyl-1-tetralone in Solvent Acetonitrile

✍ Coppens, G.; Kevill, Dennis N.; Cromwell, Norman H. 📂 Article 📅 1962 🏛 American Chemical Society 🌐 English ⚖ 245 KB

Samarium(II) iodide promoted reductive r

Samarium(II) iodide promoted reductive ring opening reaction of cyclopropane-1,1-dicarboxylic esters. Synthesis of substituted 5-Pentanolides from carbonyl compounds and dimethyl cyclopropane-1,1-dicarboxylate

✍ Tsuneo Imamoto; Toshihiko Hatajima; Takeshi Yoshizawa 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 217 KB

Homogeneous WGS Reaction Promoted by Rho

Homogeneous WGS Reaction Promoted by Rhodium Carbonyls in Aqueous Pyridine: An Acid-Cocatalyzed Reaction Which Proceeds to the Complete Consumption of Water and Is Inhibited by Chloride Ions

✍ Fachinetti, Giuseppe; Fochi, Giovanni; Funaioli, Tiziana 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 512 KB

Elimination Reactions of α-Halogenated K

Elimination Reactions of α-Halogenated Ketones. X. 1a Extent of Concurrent Substitution Reaction Accompanying Chloride Ion-promoted Elimination from 2-Benzyl-2-halogeno-4,4-dimethyl-l-tetralones in Solvent Acetonitrile

✍ Kevill, Dennis N.; Coppens, Guillaume A.; Cromwell, Norman H. 📂 Article 📅 1963 🏛 American Chemical Society 🌐 English ⚖ 318 KB