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Involvement of Singlet Oxygen in Cytochrome P450-Dependent Substrate Oxidations

✍ Scribed by Mayuko Osada; Yuhko Ogura; Hiroyuki Yasui; Hiromu Sakurai

Book ID
115584483
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
80 KB
Volume
263
Category
Article
ISSN
0006-291X

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## Abstract Cytochrome P450 (P450) enzymes catalyze a variety of oxidation and some reduction reactions, collectively involving thousands of substrates. A general chemical mechanism can be used to rationalize most of the oxidations and involves a perfenyl intermediate (FeO^3+^) and odd‐electron che