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InVivo Release of 14C-Labelled Phenolic Groups from Intact Dietary Spinach Cell Walls During Passage Through the Rat Intestine

✍ Scribed by Buchanan, Callum J; Wallace, Graham; Fry, Stephen C; Eastwood, Martin A


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
918 KB
Volume
71
Category
Article
ISSN
0022-5142

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✦ Synopsis


Feruloyl and p-coumaroyl groups in spinach cell walls (CW) were labelled using [14C]cinnamic acid and fed to rats. In the caecum and colon, ferulic acid (FA) and p-coumaric acid (PCA) were released from the CW. Few feruloyl or coumaroyl groups remained in the CW to be excreted in faeces, and thus the presence of simple phenol-sugar esters provided little protection of the polysaccharides to enzymic attack. Some oxidatively coupled phenols were also released but a portion remained in the CW. The oxidatively coupled phenols accumulated in the gut whereas the FA and PCA were absorbed by the rat. Thus enzyme-resistant fragments, containing oxidatively coupled phenols (and possibly sugar residues), may survive microbial attack by rat intestinal bacteria.