With the scanning tunneling microscope (STM) it became possible to perform controlled manipulations down to the scale of small molecules and single atoms, leading to the fascinating aspect of creating manmade structures on atomic scale. Here we present a short review of our work in the last five yea
Invited Review Engineering of single molecules with a scanning tunneling microscope tip
β Scribed by Saw-Wai Hla; Karl-Heinz Rieder
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 814 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0749-6036
No coin nor oath required. For personal study only.
β¦ Synopsis
The rapid progress in molecular manipulation with a scanning tunneling microscope (STM) tip opens up entirely new opportunities in nanoscience and technology. With these advances, the ultimate chemical reaction steps such as dissociation, diffusion, adsorption, re-adsorption and bond formation processes become possible to be performed by using the STM tip at the single molecule level with an atomic scale precision. By using a variety of manipulation techniques in a systematic and step-by-step manner, a complete chemical reaction sequence has been induced with the STM tip leading to the synthesis of molecules on an individual basis. In this paper, various STM manipulation techniques useful in the single molecule engineering process are reviewed, and their impact on the future of nanoscience and technology is discussed.
π SIMILAR VOLUMES
In the above paper, we suggested that the observed asymmetric Z-V curves obtained with an STM on Au surfaces coated with hemiquinone monolayers represent molecular switching and rectification. Further studies have shown that films lacking these molecules sometimes exhibit Z-V curves with large disco