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Investigations on the Iron-Catalyzed Asymmetric Sulfide Oxidation.

โœ Scribed by Julien Legros; Carsten Bolm

Publisher
John Wiley and Sons
Year
2006
Weight
34 KB
Volume
37
Category
Article
ISSN
0931-7597

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Investigations on the Iron-Catalyzed Asy
Investigations on the Iron-Catalyzed Asymmetric Sulfide Oxidation
โœ Julien Legros; Carsten Bolm ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 167 KB

## Abstract The development of an enantioselective sulfide oxidation involving a chiral iron catalyst and aqueous hydrogen peroxide as oxidant is described. In the presence of a simple carboxylic acid, or a carboxylate salt, the reaction affords sulfoxides with remarkable enantioselectivities (up t