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Investigations on the influence of substrate geometry of flat and stepped ruthenium surfaces Ru(0001) and Ru(101̄8) on the adsorption kinetics of H2O and D2O

✍ Scribed by W. Hoffmann; C. Benndorf

Book ID: 117217160
Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 615 KB
Volume: 377-379
Category: Article
ISSN: 0039-6028
DOI: 10.1016/s0039-6028(96)01468-9

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## Abstract The kinetics of replacement of H~2~O by [Ru(NH~3~)pz]^2+^ (pz = pyrazine) in [Fe(CN)~5~H~2~O]^3−^ have been studied in various concentrated electrolyte solutions and in various water–cosolvent mixtures, at 298 K. Salt and cosolvent effects can be rationalized taking into account specifi