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Investigations on the Chemistry of Berbanes, XIII. Selective Reduction ofNormal-,Allo-,Pseudo-, andEpiallo-Depyrrolo-Yohimbone Analogues

✍ Scribed by Tóth, István ;Bozsár, Gabriella ;Szabó, Lajos ;Tamás, József ;Baitz-Gács, Eszter ;Szántay, Csaba


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
309 KB
Volume
1987
Category
Article
ISSN
0947-3440

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✦ Synopsis


Thc rcduciion of normal-. allo-, epiallo-, and pseudo-berbanoncs wcrc studied under different conditions Reduction with Nzt/al-coho1 always I d to the thermodynamically controlled products while catalytic and NitBH4 reduction resulted almost exclusively in ibe kinetically controlied compounds. An interesting correlation was observed between the MS kaagmcntation and ring C/D