𝔖 Bobbio Scriptorium
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Investigations of the Structure and Kinetics of Intermediates in Proton-Induced Alkylidyne–Isocyanide Ligand Coupling Reactions

✍ Scribed by Dr. Cecilia M. Bastos; Nancy Daubenspeck; Prof. Andreas Mayr


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
346 KB
Volume
32
Category
Article
ISSN
0044-8249

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The polymerization reactivity of isobutylene/SnCl 4 mixtures in the absence of polar solvent, was investigated in a temperature interval from Ϫ78 to 60 °C. The mixture is nonreactive below Ϫ20 °C but slow polymerization proceeds from Ϫ20 to 20 °C with the initial rate r 0 of the order 10 Ϫ5 mol ⅐ l