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Investigations of the nucleophilic displacement at the tetrahedral phosphorus - kinetic effects of the nucleophile for a given stereochemistry

✍ Scribed by Robert J.P Corriu; Gerard F. Lanneau; Dominique Leclercq

Book ID
108371931
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
727 KB
Volume
42
Category
Article
ISSN
0040-4020

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Silicon-phosphorus analogies rate contro
Silicon-phosphorus analogies rate controlling factors in SN2(P) reactions influence of the nucleophile for a given stereochemistry
✍ Robert J.P. Corriu; GΓ©rard F. Lanneau; Dominique Leclercq πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 213 KB

SN2(P) reactions of chlorophosphates, which take place with inversion of configuration, are higly dependent upon the nature of the nucleophile. On the contrary, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect. SN2(P) processes with