Investigations of the g factors for the orthorhombic Co2+ center in YBa2Cu2.7Co0.3O7−x at room temperature
✍ Scribed by Shao-Yi Wu; Guang-Duo Lu; Hua-Ming Zhang; Zhi-Hong Zhang
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 154 KB
- Volume
- 466
- Category
- Article
- ISSN
- 0921-4534
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✦ Synopsis
The anisotropic g factors g x , g y and g z for the orthorhombic Co 2+ center on the Cu(1) site in YBa 2 Cu 2.7 Co 0.3 O 7Àx at room temperature are theoretically investigated from the perturbation formulae of the g factors for a 3d 7 ion having low spin (S = 1/2) under octahedra with orthorhombic distortion. In these formulae, the contributions to the g factors from the orthorhombic crystal-fields as well as the ligand orbitals and spin-orbit coupling are taken into account based on the cluster approach. This center may be attributed to Co 2+ located in a moderately compressed oxygen octahedron with additional orthorhombic distortion. The significant decline (characterized by the reduction factor c % 0.13) of the energy separations due to the Jahn-Teller effect is suggested, by analyzing the experimental g factors. The calculated g factors based on the above contributions show good agreement with the observed values. In addition, the pronounced decrease in the intensity and the remarkable nonlinear increase in the g y of Co 2+ EPR spectra as the temperature is lowered from room temperature to 150 K are also mentioned, in view of the opening of the spin gap due to antiferromagnetic interactions.
📜 SIMILAR VOLUMES
Perovskite oxide structured (YBCO) has been Ðrst pre-YBa 2 Cu 3 O 7vx pared by carbonate precipitation and then modiÐed with palladium or ruthenium by impregnation on the perovskite oxide, while cobalt was co-precipitated simultaneously in the same pH range with perovskite oxide. After characterizat