## Abstract Photochemical cyclization and halogen abstraction reactions of secondary alkylcobaloximes 1b and 1d compared to their primary counterparts 1a and 1c show an enhanced reactivity of secondary alkylcobaloximes: Thus, cyclohexylcobaloxime 1d reacts 13 times faster with CCl~4~ than __n__1βhe
β¦ LIBER β¦
Investigations of Different Chemoselectivities in Primary, Secondary and Tertiary Amide Reactions with Sodium Borohydride
β Scribed by Jie Ren; Liang-Chun Li; Ji-Kai Liu; Hua-Jie Zhu; Charles U. Pittman Jr.
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 198 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-193X
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The reaction kinetics of carbon dioxide with four alkanolamines of industrial importance (MEA, DGA, DEA, and DIPA) have been investigated with the aid of the stopped-flow technique, allowing the determination of rate constants for carbamates formation. The constants obtained for MEA at 20Β°C and 25Β°C