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Investigations in the vitamin A series V. Some aspects of dehydration of polyenic alcohols

✍ Scribed by P. H. van Leeuwen; H. O. Huisman

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 461 KB
Volume: 80
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19610801009

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✦ Synopsis

Abstract

The facile acid‐catalysed dehydration of substituted β‐ionols, e.g. β‐C~15~‐ and β‐C~20~‐hydroxy esters, gives a substantial yield of the R (= retro) compounds and not of the corresponding β‐ionylidene compounds. This is correlated with the different properties of these molecules: almost planar configuration of R‐compounds vs. distorted β‐ionylidene derivatives.

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