✦ LIBER ✦
Investigations Concerning an Unexpected Reaction between the Dimsyl Anion ( = (Methylsulfinyl)methanide) and a γ,δ-Epoxy-ketone
✍ Scribed by René Beerli; Hans-Jürg Borschberg
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- German
- Weight
- 735 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
This term was coined with the intention to point out the analogy to the well-established notation 'vinylogous'
PI.
An inspection of molecular models suggests that the transition state leading from 7 to the elusive 'endo'product 11 would be destabilized through severe nonbonded steric interactions.