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Investigation of the trigonal-field splittings D and dependences on the local structural distortions for ZnSiF6·6H2O: Mn2+ (Ni2+)

✍ Scribed by Zhao-Min Li; Wei-Li Shuen


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
333 KB
Volume
222
Category
Article
ISSN
0921-4526

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On the assignment of SiH and SiD stretch
✍ D.C. McKean 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 592 KB

AImtract--Assignments of v(SiH) and v(SiD) modes in SiHX3, SiH2X 2 and SiH3X compounds are surveyed. With a few exceptions, v(SiH)/v(SiD) ratios are found to be those expected on the basis of harmonic local mode calculations, if v(SiD) values are first divided by a factor R which normally lies in th