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Investigation of the three-dimensional structure of 7,7-dihalo-3∶4-benzo[4,l,0]bicyclo-3-heptenes

✍ Scribed by B. A. Arbuzov; A. N. Vereshchagin; S. G. Vul'fson; É. M. Kharicheva


Book ID
112422984
Publisher
Springer
Year
1972
Tongue
English
Weight
352 KB
Volume
21
Category
Article
ISSN
1573-9171

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Thermal rearrangements of 7,7-dihalo-tra
✍ Paul G Gassman; Sangdon Han; Leonard J Chyall 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 216 KB

Derivatives of trans-bicyclo[4.1.0]hept-3-ene with chlorine and bromine substituents the 7 position were synthesized and their thermal rearrangements were examined. Thermolysis of the dichloride leads to the formation of the cis-fused isomer, while heating the dibromide results in ring-expanded prod