Cationic and Neutral Diphenyldiazomethan
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Helmut Werner; Michael E. Schneider; Marco Bosch; Justin Wolf; Jan H. Teuben; Au
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Article
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2000
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John Wiley and Sons
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English
β 256 KB
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Cationic rhodium(i) complexes cis-[Rh(acetone) 2 (L)(L')] (2: L L' C 8 H 14 ; 3: L C 8 H 14 ; L' PiPr 3 ; 4: L L' PiPr 3 ), prepared from [{RhCl-(C 8 H 14 ) 2 } 2 ] and isolated as PF 6 salts, catalyze the CΓC coupling reaction of diphenyldiazomethane with ethene, propene, and styrene. In most cases