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Investigation of the structure and catalytic activity in olefin cyclopropanation of neutral and cationic dicopper complexes of 3,5-bis(pyridinylimino)benzoic acid

✍ Scribed by Dimitrios Tzimopoulos; Stefano Brenna; Agnieszka Czapik; Maria Gdaniec; Attilio Ardizzoia; Pericles D. Akrivos


Book ID
113642378
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
928 KB
Volume
383
Category
Article
ISSN
0020-1693

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Cationic rhodium(i) complexes cis-[Rh(acetone) 2 (L)(L')] (2: L L' C 8 H 14 ; 3: L C 8 H 14 ; L' PiPr 3 ; 4: L L' PiPr 3 ), prepared from [{RhCl-(C 8 H 14 ) 2 } 2 ] and isolated as PF 6 salts, catalyze the CΓ€C coupling reaction of diphenyldiazomethane with ethene, propene, and styrene. In most cases