Investigation of the Reactivity of Epoxide Monomers in Photoinitiated Cationic Polymerization
โ Scribed by Bulut, Umut; Crivello, James V.
- Book ID
- 118260949
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 411 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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๐ SIMILAR VOLUMES
## Abstract Difunctional epoxy monomers have been polymerized cationically by UV irradiation in the presence of a triarylsulfonium photoinitiator. The curing process was followed quantitatively by monitoring the disappearance of the epoxy group by infrared spectroscopy and the insolubilization and
A series of epoxy alcohols were prepared by simple, straightforward methods. These compounds were very reactive monomers that polymerized rapidly on UV irradiation in the presence of cationic photoinitiators. The kinetics of the cationic photopolymerization of these monomers were studied with diaryl