Investigation of the Reaction of Dithiocarbamic Acid Salts with Aromatic Aldehydes
β Scribed by Ziyaei Halimehjani, Azim; Hajiloo Shayegan, Mojtaba; Hashemi, Mohammad Mahmoodi; Notash, Behrooz
- Book ID
- 120870525
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 529 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
Arylation reaction of aromatic aldehydes with arylboronic acids proceeded smoothly in the presence of a base and catalytic amount of a nickel salt, Ni(ClO 4 ) 2 Γ6H 2 O, in toluene/IPA = 5:1 or IPA to afford corresponding diarylmethanols in good to excellent yields.
1n 1935 Krohnke' reported that benzaldehyde condensed with Z-benzylisoquinolinium bromide (1, R = CHzC9H5), in the presence of alkali, to yield, after acidification with HBr, an alcohol, formulated as (2). Since it is probable that the pseudobase (3, R = CB2CSH5) is formed from (1) and the alkali,