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INVESTIGATION OF THE REACTION BETWEEN DIALKYLPHOSPHINES AND CARBON TETRACHLORIDE. PART II

โœ Scribed by Majewski, Piotr

Book ID
118205408
Publisher
Taylor and Francis Group
Year
1994
Tongue
English
Weight
487 KB
Volume
86
Category
Article
ISSN
1042-6507

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Kinetics of the metathetical reaction be
Kinetics of the metathetical reaction between carbon tetrachloride and toluene
โœ Diana Curcio Shoulders; T. J. Hardwick; Donald C. Ketter; George W. Pukanic ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 486 KB

A metathetical reaction between carbon tetrachloride and toluene to give benzyl chloride and chloroform occurs at temperatures above 200ยฐC (k = 4.8 X 1Olo e-82,m/RT cc mole-'sec-'). The reaction does not involve free radicals, as is shown by the kinetic behavior of the system, by the lack of effect