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Investigation of the rate-controlling step of the water gas shift reaction with use of various isotopic tracers

✍ Scribed by Oki, Shoichi; Mezaki, Reiji


Book ID
126116441
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
892 KB
Volume
27
Category
Article
ISSN
0888-5885

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Shift of the rate-determining step in a
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## Abstract A consecutive single‐route reaction is considered. When two (groups of) steps compete in controlling the overall reaction rate, there exists a general rule that the earlier step in the flow of the overall reaction tends to be rate‐determining with the increase of the reaction affinity.