Cu 0.5 Zn 0.5 Mn 2 O 4 spinel-lattice catalyst has been studied for methanol decomposition by in situ infrared (IR) spectroscopy analysis and micro reactor study. Methoxy species is formed by dissociative adsorption of methanol which subsequently converts into formate species via step-wise dehydroge
✦ LIBER ✦
Investigation of the Mn2+-F− distance for Mn2+ in fluoride lattices with hexahedral coordination
✍ Scribed by M.T. Barriuso; M. Moreno
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 399 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The Mn'*-F-distance for hln*+-doped CaFa, CdF-,, SrFa and BaFa is derived from the experimental isotropic superhyperfme constant As. The results obtained indicate the existence of inwards relasation processes in all these cases, as well as values of the Mn2*-F-distance which are 10.1 A IarSer than those found for systems with [hinFs] 4-units. This allows one to explain the low IODq values recently found by Alonso an Alcalri in CdFa: bin'+ and CaFa: hfn'+.
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