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Investigation of the Mn2+-F− distance for Mn2+ in fluoride lattices with hexahedral coordination

✍ Scribed by M.T. Barriuso; M. Moreno


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
399 KB
Volume
112
Category
Article
ISSN
0009-2614

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✦ Synopsis


The Mn'*-F-distance for hln*+-doped CaFa, CdF-,, SrFa and BaFa is derived from the experimental isotropic superhyperfme constant As. The results obtained indicate the existence of inwards relasation processes in all these cases, as well as values of the Mn2*-F-distance which are 10.1 A IarSer than those found for systems with [hinFs] 4-units. This allows one to explain the low IODq values recently found by Alonso an Alcalri in CdFa: bin'+ and CaFa: hfn'+.


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