Two-and three-layer composite latex particles were used to prepare rubbertoughened poly(methyl methacrylate) (RT-PMMA). The interfacial thicknesses of the multilayered particles were varied by using different emulsion polymerization synthesis techniques. The resulting interphases were previously cha
Investigation of the micromechanical deformation behavior of transparent toughened poly(methylmethacrylate) modified with core–shell particles
✍ Scribed by J. Laatsch; G.-M. Kim; G. H. Michler; T. Arndt; T. Süfke
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 311 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1042-7147
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✦ Synopsis
The micromechanical deformation behavior of transparent rubber-toughened poly(methylmethacrylate) (RTPMMA) was investigated by electron microscopy. With increasing volume fraction of particles (from 4 vol% to 35 vol%) RTPMMA showed a transition of deformation mode from brittle to ductile. In both cases the particles deform through fibrillized cavitation processes. The dominant toughening mechanism in the specimen containing 4 vol% particles was multiple crazing triggered by fibrillized cavitated particles, whereas in the specimen with 35 vol% particles the specimen deformed by shear flow of matrix material between the fibrillized particles. From the results of an in situ deformation test in high-voltage electron microscopy it can be deduced that interparticle distance plays decisive role on the transition of deformation mode.
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