Investigation of the Interaction of Quartz with Hydrogen under Supply of Mechanical Energy (II) Investigation by IR Spectroscopy
โ Scribed by Dr. H. Geissler; Dr. H.-P. Hennig; Dr. D. Kunath; Dr. habil. I. Ebert; Dr. V. Hopfe; Prof. Dr. habil. U. Steinike
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 396 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0232-1300
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โฆ Synopsis
Abstract
Infrared investigations demonstrate a chemical interaction of quartz in hydrogen atmosphere during mechanical activation:
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By means of the SiH stretching band the number of formed SiHโgroups is estimated as a function of the period of activation. of activation. This number is more than one order of magnitude less than the total number of adsorbed molecules.
๐ SIMILAR VOLUMES
FT-IR spectroscopy and a special mathematical program were used for the real-time monitoring of the mechanistic path of the reaction of S-ethyl-N,Ntetraethyldiamidothiophosphite with [CpMn(CO)-2NO]+BF;. The formation of a few intermediates is described.