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Investigation of the interaction in the systems C2H2-HCl and C2H2-Cl2at low temperatures by the method of IR spectroscopy

✍ Scribed by Ya. M. Kimel'feld; É. V. Lumer; A. P. Shvedchikov

Book ID
112422452
Publisher
Springer
Year
1973
Tongue
English
Weight
267 KB
Volume
22
Category
Article
ISSN
1573-9171

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Tunneling in the C2HH2 reaction at low
Tunneling in the C2HH2 reaction at low temperature
✍ Eric Herbst 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 422 KB

Low-temperature experiments on the ion-molecule reaction between NH: and H2 show that this reaction can occur with an appreciable rate at very low temperature ( Q: 100 K) despite the existence of an activation energy barrier. Theoretical calculations have confirmed the mechanism for the process at l