✦ LIBER ✦

Investigation of the gas phase reaction of dinitrogen pentoxide with water vapor

✍ Scribed by George M. Sverdrup; Chester W. Spicer; Gerald F. Ward

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 638 KB
Volume: 19
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550190304

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✦ Synopsis

The gas phase reaction of NzOs with water vapor was investigated in a 17.3-m' Teflon lined chamber. Temporal concentration profiles for ozone, total nitrogen oxides, and nitrogen dioxide were measured. Concentration profiles for N2OS and HNO, were calculated from a combination of measurements of nitrogenous species. A kinetic mechanism with an adjustable value for the rate constant of NzOs + H,O was used to model the experiments. From this analysis an upper limit value of k s 4 x 1 0 ~ ' ppm min-' for the gas phase reaction N,O, + HzO + 2HNOi was derived.

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