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Investigation of the Ferroelastic Domain Structure of TMCC by Means of Nuclear Magnetic Resonance Spectroscopy

✍ Scribed by S. Mulla-Osman; D. Michel; G. Völkel; Z. Czapla


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
97 KB
Volume
219
Category
Article
ISSN
0370-1972

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✦ Synopsis


The twin domain structure of the ferroelastic P2 1 /m phase of TMCC is studied by means of NMR. Six orientational domains are verified from the NMR rotational pattern at 115 K in contrast to the expected number of three for a classical 6/mF2/m transition. The rotational angle Q between the epitaxially grown twins is calculated from the strain tensors of the three Aizu orientation states applying the algebraic approach developed by Shuvalov et al. The theoretical value Q = 3.5 o is in very good correspondence to the experimentally observed rotation angle Q exp = 4 o of the EFG tensors.


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