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Investigation of the catalyst system tungsten hexachloride/tetramethyltin; reduction of tungsten hexachloride during the alkylation step

✍ Scribed by E. Thorn-Csányi; M. Kessler

Book ID
103693694
Publisher
Elsevier Science
Year
1991
Weight
456 KB
Volume
65
Category
Article
ISSN
0304-5102

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Tungsten hexachloride alone as a catalys
Tungsten hexachloride alone as a catalyst for the metathetic polymerization of cyclic olefins
✍ A.J. Amass; T.A. McGourtey; C.N. Tuck 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 121 KB

The polymerization of cyclic olefins may be initiated by tungsten hexachloride alone. The rate of polymerization is less than that normally obtained with bimetallic catalysts but the equilibrium conversion monomer is of the same order.