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Investigation of reaction kinetics by wavefront analysis

✍ Scribed by E. Fiolitakis; U. Hoffmann; H. Hofmann

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
596 KB
Volume
34
Category
Article
ISSN
0009-2509

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✦ Synopsis

A new techmque for ktnetlc mvestlgatlons m fixed bed reactors, wave front analysis, LS Introduced m tlus paper Use IS made of memann's mtegratron method to solve the hneaed hyperbohc equations representmg the dynanucs of a homogeneous reaction m a packed tubular reactor It 1s shown how the analysis of the front of the faster disturbance, m thrs system the concentration step, can be used for kmetlc mvestlgauons Wave front analysis 1s generahzed for non-lmear systems through P~card's Iteration technrque PROBLEM

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Kinetic investigations in heterogeneous
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✍ E. Fiolitakis; U. Hoffmann; H. Hofmann πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 515 KB

In this paper the previously Introduced wavefront analysis IS extended to heterogeneous reactlon systems, which conslst of several reaction steps It IS shown how three mamly mformations obtamed at the wavefront, namely the dampmg of the wavefront, the time-gradients at the wavefront and the propagat

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It has been demonstrated that durmg dynamic operation of the low temperature watergas shift reactlon on the wavefront the CO,-production IS faster than the H,-productlon For a catalyst pretreated for several hours with a mixture of CO/N, its re-oxldatlon by a mixture of H,O/CO/N, IS a slow process,