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Investigation of ion-pair precipitates of selected alkoxylates and complex salts of specific metal cations by liquid secondary ion mass spectrometry

✍ Scribed by Rafał Frański; Andrzej Szymański; Błażej Gierczyk; Jan Chlebicki; Magdalena Frańska

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
189 KB
Volume
37
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Liquid secondary ion (LSI) mass spectra of ion‐pair precipitates obtained for Triton X‐100 with strontium, lead, cadmium and mercury tetraphenylborates and for selected butoxylene–ethoxylene monoalkyl ethers with barium tetraiodobismuthate(III) are discussed. On the basis of LSI mass spectra, recorded in both positive and negative modes, the formulae of the ion‐pair precipitates were determined. On the basis of B/E mass spectra, the fragmentation routes of [M − H + Ba]^+^ ions for butoxylene–ethoxylene monoalkyl ether complexes of barium and [M − H + Cd]^+^ ions for the Triton X‐100 complex of cadmium are proposed. Copyright © 2002 John Wiley & Sons, Ltd.

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