Investigation of formic acid oxidation on palladium in acidic solutions by on-line mass spectroscopy
β Scribed by V. Solis; T. Iwasita; A. Pavese; W. Vielstich
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 422 KB
- Volume
- 255
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
Electra-oxidation of HCOOH on Pd in acidic medium is studied by cyclic voltammetry. Homogeneous oxidation of HCOOH by Pd(I1) ions is followed by potential decay at open circuit and by spectrophotometry. An enhancement of HCOOH electro-oxidation current is found by Pd( II) addition to the working sol
Ahstraet-The electro-oxidation of formic acid and its derivatives-formamide and dimethylformamid~has been studied at a porous platinum electrode in 0.05M H,SO, with special attention to common features of their electrochemical behaviour. It is shown that the contribution of bulk reactions to the ele