Investigation of copper(II)-Ethylenediaminetetraacetate complexation by window factor analysis of ultraviolet spectra
β Scribed by Wei Den; Edmund R. Malinowski
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 550 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0886-9383
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The structures of two binuclear copper complexes of N,N 0 ,N 00 ,N 000 -tetrakis(2-aminoethyl)-1,4,8,11tetraazacyclotetradecane (TAEC) in crystal form and in aqueous solution were determined by DV-Xa analysis of XANES (x-ray absorption near-edge structure) spectra. The results revealed that a Br -is
The i.r. spectra of bis(ethylenediamine) and bis(trimethylenediamine) complexes of Cu(II) have been measured in the wave number region of 4000-250 cm-t. Vibrational assignments have been made regarding the individual rings in both complexes. A normal coordinate analysis was performed using a modifie