Progress in the analysis of the infrared spectrum of CH 3 OH in the 930 -1450 cm Ϫ1 region has led to assignments, confirmations, or new insights for a number of far-infrared laser (FIRL) transition systems optically pumped by CO 2 lasers. Many of the systems involve FIRL transitions among the CO-st
✦ LIBER ✦
Investigation of C–O Stretching Band of CD3OH: Assignments of Far-Infrared Laser Lines
✍ Scribed by J.C.S. Moraes
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 176 KB
- Volume
- 185
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
We have investigated the high-resolution Fourier transform spectrum of the C -O stretching fundamental band of CD 3 OH in order to assign far-infrared ( FIR) laser transitions. The absorption spectrum was analyzed by means of the ''Ritz'' program, which calculates the energy level values directly from the Rydberg-Ritz combination principle. We have also used the ''LaseRitz'' program to facilitate the assignment of the FIR laser lines. As a consequence we could determine 12 new assignments, confirming 4 previously proposed ones and predicting new FIR laser emissions.
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