## Abstract Complete ^13^C spectral assignments were made for 1‐ and 2‐R‐naphthalenes (R = Me, Et, __i__‐Pr, __t__‐Bu) in CDCl~3~ solution (5 mol%) by the use of 2D techniques including 2D INADEQUATE. Contradictory assignments from the literature were clarified and incomplete data completed. Substi
Investigation of benzimidazoles: II—the influence of substituents and solvents on the 1H and 13C NMR chemical shifts of 2-substituted 1,3-dimethylbenzimidazolium perchlorates
✍ Scribed by L. I. Larina; T. I. Vakul'skaya; A. V. Filatov; B. I. Istomin; E. F. Shibanova; V. A. Lopyrev; M. G. Voronkov
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 356 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The influence of substituents on ^1^H and ^13^C NMR chemical shifts of 2‐substituted 1,3‐dimethylbenzimidazolium perchlorates in different solvents has been investigated. It has been shown that the transmission of the electronic effects of the substituents in benzimidazoles and their quaternary salts are almost the same. The nature of the solvent influences only the intensity of the transmission of the electronic effects of substituents in 2‐substituted 1,3‐dimethylbenzimidazolium perchlorates.
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