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Investigation of anhydrous metal(II) nitrates. I. Syntheses and crystal structures of Mg(NO3)2, Co(NO3)2 and Ni(NO3)2, with a stereochemical discussion

โœ Scribed by Giester, Gerald; Lengauer, Christian L.; Wildner, Manfred; Zemann, Josef

Book ID
115448175
Publisher
Oldenbourg Wissenschaftsverlag
Year
2008
Tongue
English
Weight
500 KB
Volume
223
Category
Article
ISSN
2194-4946

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Investigation of low-hydrated metal(II)
Investigation of low-hydrated metal(II) nitrates. Syntheses and crystal structures of Zn(NO 3 ) 2 ยท H 2 O and M(II)(NO 3 ) 2 ยท 2 H 2 O (M = Mg, Mn, Co, Ni)
โœ Wildner, Manfred; Giester, Gerald; Lengauer, Christian L.; Zemann, Josef ๐Ÿ“‚ Article ๐Ÿ“… 2012 ๐Ÿ› Oldenbourg Wissenschaftsverlag ๐ŸŒ English โš– 824 KB

## Abstract Crystals of Zn(NO~3~)~2~ยท H~2~O and Mn(NO~3~)~2~ยท 2 H~2~O were synthesized by heating melts of the respective penta- or hexahydrates. Single crystal X-ray diffraction of the two highly hygroscopic phases reveals new sheet-structure types: Zn(NO~3~)~2~ยท H~2~O [__Pbca__,__a__= 9.722(1),__