Investigation into the performance of a Co–Mo based sour shift catalyst using simulated coal-derived syngases
✍ Scribed by San Shwe Hla; G.J. Duffy; L.D. Morpeth; A. Cousins; D.G. Roberts; J.H. Edwards
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 592 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0360-3199
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✦ Synopsis
The performance of a commercially-available sour shift catalyst (SSC1) under selected syngas compositions was investigated and kinetic parameters were obtained. The watergas shift experiments were carried out in a differential reactor using simulated syngases containing a constant level of H 2 S concentration of 1000 ppm on a wet basis at 450 C and atmospheric pressure. The following kinetic relationship has subsequently been developed to describe the performance of catalyst SSC1 at a reaction temperature of 450 C (723 K) and atmospheric pressure using a powerelaw model: