Investigating polymer blend miscibility with forward recoil spectrometry

✍ Scribed by Nicole N. Pellegrini; Russell J. Composto; Karen I. Winey

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 122 KB
• Volume: 38
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(20000601)38:11<1547::aid-polb150>3.0.co;2-l

✦ Synopsis

We tested forward recoil spectrometry (FRES) as a method to determine miscibility by measuring coexistence compositions in binary polymer blends. In this study, equilibrium phase compositions were determined for a compositionally symmetric poly(styrene-ran-methyl methacrylate) random copolymer (S 0.49 -r-MMA) and two homopolymers, deuterated polystyrene (dPS) and deuterated poly(methyl methacrylate) (dPMMA). Sample preparation, film dewetting, and beam damage were addressed, and the results for these polymer blends were in good agreement with those obtained through other experimental techniques. Deuteration had a strong effect on the miscibility of the dPS/S 0.49 -r-MMA and dPMMA/S 0.49 -r-MMA blends, to the extent that the asymmetric miscibility observed separately for the PS/S 0.49 -r-MMA and PMMA/S 0.49r-MMA blends was not found. Although this deuteration effect may limit the applicability of FRES for some polymer systems, the accuracy with which phase compositions can be determined with FRES makes it an attractive alternative to other less quantitative methods for investigating blend miscibility.