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Inversion-Recovery of Nitroxide Spin Labels in Solution and Microheterogeneous Environments

✍ Scribed by Koptyug, Igor V.; Bossmann, Stefan H.; Turro, Nicholas J.


Book ID
126226906
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
401 KB
Volume
118
Category
Article
ISSN
0002-7863

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Information on the rotational motion of various types of spin-labelled long-chain nitroxides was obtained from the anisotropic ESR signals. By varying the position of the nitroxide moiety along the chain, the intrinsic flexibility of molecular chain was examined. The rotational correlation times (t,