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Inversion of the substituent effects on the rates of ArSC1 AdE-reactions with styrenes

✍ Scribed by Ivan V. Bodrikov; A.V. Borisov; L.V. Chumakov; Nikolai S. Zefirov; W.A. Smit


Book ID
108382248
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
270 KB
Volume
21
Category
Article
ISSN
0040-4039

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Substituent effects on the redox reactio
✍ Karl M Kadish; Mark M Morrison πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science βš– 543 KB

The effect of substituents on pi radical reactions of para-substituted tetraphenylporphyrins was investigated by cyclic voltammetry in methylene chloride. In all cases electron donating substituents produced a more difficult reduction and an easier oxidation. Plots of E1/2 vs. a yielded Hammett line