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Inversion of Optical Activity of Chiral Polythiophene Aggregates by a Change of Solvent

โœ Scribed by Langeveld-Voss, B. M. W.; Christiaans, M. P. T.; Janssen, R. A. J.; Meijer, E. W.


Book ID
127110013
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
63 KB
Volume
31
Category
Article
ISSN
0024-9297

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The chiroptical properties of a novel, optically active regioregular poly[3-(4-((R)-4-ethyl-2-oxazolin-2-yl)phenyl)thiophene] (poly-1) were investigated in mixtures of a good solvent, chloroform, and a variety of poor solvents using CD spectroscopy. Most poor solvents induced CD on poly-1 with simil