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Inversion of configuration in the bromination of vinylic mercurials

โœ Scribed by Casey, Charles P.; Whitesides, George M.; Kurth, Jean


Book ID
126438254
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
573 KB
Volume
38
Category
Article
ISSN
0022-3263

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An interest in the synthetic utility of a-bromovinyl sulfones,' particularly with derivatives of defined stereochemistry, has led us to examine closely the stereochemical outcome of the bromination-dehydrobromination sequence for the conversion of L to 2. In this communication we wish to H R-CH=C' -