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Inverse effects of alkyl substitution on three-electron SN2 reactions

✍ Scribed by Dinnocenzo, J. P.; Lieberman, D. R.; Simpson, T. R.


Book ID
121399695
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
303 KB
Volume
115
Category
Article
ISSN
0002-7863

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Reactivities of methyl naphthalene-2-sulfonate, MeONs, and its 6-alkyl derivatives, alkyl=Me, n-C(6)H(13) and n-C(12)H(25), 6-Me-MeONs, 6-Hex-MeONs, and 6-Do-MeONs, respectively, are compared for reactions in cetyl trialkylammonium bromide micelles, n-C(16)H(33)NR(3)Br, R=Me, Et, n-Pr, n-Bu, CTABr,