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Inverse Axial-Ligand Effects in the Activation of H2O2 and ROOH by an MnIII Corrolazine

✍ Scribed by David E. Lansky; Amy A. Narducci Sarjeant; David P. Goldberg


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
122 KB
Volume
118
Category
Article
ISSN
0044-8249

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New Dinuclear MnIII Compounds with 2-MeC
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## Abstract Four new dinuclear Mn^III^ complexes with the general formula [{Mn(bpy)L}(μ‐RCOO)~2~(μ‐O){Mn(bpy)Lβ€²}]^__n+__^ (bpy =2,2′‐bipyridine) have been synthesized with RCOO = 2‐MeC~6~H~4~COO (1, 2) and 2‐FC~6~H~4~COO (3, 4); the counteranion could be NO~3~^–^ (1, 3) or ClO~4~^–^ (2, 4), and a m