✦ LIBER ✦

Introduction of an Optically Active Ligand into Transition Metal Complexes with Five Independent Ligands

✍ Scribed by Dr. Ernesto Colomer; Prof. Dr. Robert J. P. Corriu; Dr. Ing. André Vioux

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 231 KB
Volume: 20
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198104761

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of bromotrichloromethane with styrene in 2 : 1 ethanol-benzene, in the presence of an optically active phosphane-rhodium complex [( -)-diop]RhClf3I (0.30 mmol) at 80°C for 18 h, gave the 1 : 1-adduct ( I ) in 26% yield. The adduct (1) showed an optical rotation of

📜 SIMILAR VOLUMES

Optically active transition metal comple

Optically active transition metal complexes, XLIV. The nature of the chiral intermediates involved in the racemization and ligand exchange reactions of optically active manganese compounds

✍ H. Brunner; W. Steger 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 305 KB 👁 1 views

Transition-Metal Complexes of the Optica

Transition-Metal Complexes of the Optically Active Cyclopentadienyl Ligand PinCp*: Crystal Structure of (SRe)-(η5-PinCp*)Re(NO)(PPh3)[CONHCH(CH3)C10H7]

✍ Albrecht Salzer; Annegret Hosang; Jutta Knuppertz; Ulli Englert 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 403 KB 👁 1 views

The synthesis of (η 5 -PinCp\*)Re (CO) 3 [PinCp\* = tetra-analysis. By treating the (S Re )-amide with CF 3 CO 2 H and NaBF 4 , (S Re )-(PinCp\*)Re(CH 3 )(NO)(PPh 3 ) can be generated. methyl(pinanyl)cyclopentadienyl] is described. Successive substitution of two CO ligands by NO + and PPh 3 generate