Introduction of amino, aliphatic, and aliphatic carboxylic acid side groups onto poly(arylene ether sulfone)s via transimidization reactions
✍ Scribed by C. G. Herbert; H. Ghassemi; A. S. Hay
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 175 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0887-624X
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✦ Synopsis
A versatile approach for the functionalization of a bisphenolic monomer, 3,8-bis(4-hydroxyphenyl)-N-phenyl-1,2-naphthalimide ( 1) as well as its corresponding poly(N-phenyl imido aryl ether sulphone) via transimidization reactions with hydrazine monohydrate, aliphatic amines, and an amino acid (11-amino undecanoic acid) is reported. The reactions proceeded in high conversion and high isolated yield to the desired novel functionalized monomers or polymers with N-amino, N-aliphatic, and Naliphatic acid pendant groups. The N-amino functionalized monomer, 2, was reacted cleanly with naphthalic anhydride to form a bisimide. Polymers with phthalimide ( 7), 3-carboxy phthalimide (9), and bisphenol-A-(monoimide monoanhydride) ( 8) pendant groups were also formed by imidization of 6. A polymer with a cyclopropyl amide functional group, 10, was formed by reacting 6 with cyclopropyl carbonyl chloride. A brief description of the transimidization reactions and the properties of the functionalized polymers is included.