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Introduction D'Un Systeme “Cage” Derive De L'Adamantane Dans Les Acides Carboxyliques, Par Alkylation En Catalyse Par Transfert De Phase Et Par Une Methode Non Catalytique

✍ Scribed by Mir Hedayatullah


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
239 KB
Volume
98
Category
Article
ISSN
0037-9646

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✦ Synopsis


The syntheses of new carboxylic esters of general type RC02-CH2CO-Ad (Ad = I-adamantyl), where R may be aliphatic or aromatic, have been achieved in high yield by reaction of the corresponding acides with an appropriate derivative of adamantane under phase-transfer conditions or by a noncatalytic procedure. The influence of the lipophilicity of the catalyst on the course of the alkylation of benzoic acide is discussed.


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