Introduction D'Un Systeme “Cage” Derive De L'Adamantane Dans Les Acides Carboxyliques, Par Alkylation En Catalyse Par Transfert De Phase Et Par Une Methode Non Catalytique

✍ Scribed by Mir Hedayatullah

• Publisher: Wiley (John Wiley & Sons)
• Year: 2010
• Weight: 239 KB
• Volume: 98
• Category: Article
• ISSN: 0037-9646
• DOI: 10.1002/bscb.19890980209

✦ Synopsis

The syntheses of new carboxylic esters of general type RC02-CH2CO-Ad (Ad = I-adamantyl), where R may be aliphatic or aromatic, have been achieved in high yield by reaction of the corresponding acides with an appropriate derivative of adamantane under phase-transfer conditions or by a noncatalytic procedure. The influence of the lipophilicity of the catalyst on the course of the alkylation of benzoic acide is discussed.