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Introducing Axial Chirality into Mesoionic 4,4′-Bis(1,2,3-triazole) Dicarbenes

✍ Scribed by Aizpurua, Jesus M.; Sagartzazu-Aizpurua, Maialen; Monasterio, Zaira; Azcune, Itxaso; Mendicute, Claudio; Miranda, Jose I.; García-Lecina, Eva; Altube, Ainhoa; Fratila, Raluca M.


Book ID
115457525
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
580 KB
Volume
14
Category
Article
ISSN
1523-7060

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4-Amino-3,5-bis(4-pyridyl)-1,2,4-triazol
✍ Guo, Ya-Mei ;Du, Miao 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 280 KB

The two pyridine rings in the title compound, C 12 H 10 N 6 , form dihedral angles of 35.7 (2) and 16.8 (2) with the central triazole ring. The molecules exist as centrosymmetrically related dimers and form a three-dimensional network through intermolecular NÐHÁ Á ÁN hydrogen bonds.