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Intrinsic reactivity of metal–hydroxide complexes: O–H bond activation and adduct formation in gas-phase reactions of Cp2ZrOH+

✍ Scribed by David E. Richardson; G.H.Lisa Lang; Elisa Crestoni; Matthew F. Ryan; John R. Eyler


Book ID
104432183
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
314 KB
Volume
204
Category
Article
ISSN
1387-3806

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The Dependence on H2O and on NH3 of the
✍ Edwin J. Hamilton Jr.; Ruey-Rong Lii 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 538 KB

Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm