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Intrinsic carbon-13 NMR solvent shifts in hydrocarbons. Relevance of long range substituent parameters

✍ Scribed by A. R. N. Wilson; L. J. M. van de Ven; J. W. de Haan

Publisher: John Wiley and Sons
Year: 1974
Tongue: English
Weight: 227 KB
Volume: 6
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270061111

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✦ Synopsis

Abstract

Carbon‐13 NMR chemical shifts have been measured in a number of binary mixtures of normal alkanes. Intrinsic solvent shifts are deduced from the shifts and the relevance of some small substituent effects in alkanes is discussed. A comparison is made between solvent effects and thermally induced chemical shift differences in alkanes.

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